Journal Article

Print(0)

Acta crystallographica.Section E, Structure reports online

Acta Crystallogr.Sect.E.Struct.Rep.Online

10-May

70

Pt 6

m202

3

LR: 20140620; JID: 101089178; OID: NLM: PMC4051086; 2014/06/01 [ecollection]; 2014/04/29 [received]; 2014/04/30 [accepted]; 2014/05/10 [epublish]; epublish

United States

1600-5368; 1600-5368

PMID: 24940195

eng

Journal Article

10.1107/S1600536814009805 [doi]

Unknown(0)

24940195

In the title hydrated salt, (C5H14N2)2[Bi2Br10].2H2O, the com-plete [Bi2Br10](4-) biocta-hedron is generated by crystallographic inversion symmetry. The diprotonated piperazine ring adopts a chair conformation, with the methyl group occupying an equatorial position. In the crystal, the tetra-anions and water mol-ecules are linked by O-Hcdots, three dots, centeredBr and O-Hcdots, three dots, centered(Br,Br) hydrogen bonds to generate [100] chains. The chains are crosslinked by N-Hcdots, three dots, centeredBr, N-Hcdots, three dots, centeredO and C-Hcdots, three dots, centeredBr hydrogen bonds originating from the piperazinediium dications, thereby forming a three-dimensional network.

Essid,M., Roisnel,T., Marouani,H.

Laboratoire de Chimie des Materiaux, Faculte des Sciences de Bizerte, 7021 Zarzouna Bizerte, Tunisia.; Centre de Diffractometrie X, UMR 6226 CNRS, Unite Sciences Chimiques de Rennes, Universite de Rennes I, 263 Avenue du General Leclerc, 35042 Rennes, Fra

20140510

PMC4051086

http://vp9py7xf3h.search.serialssolutions.com/?charset=utf-8&pmid=24940195

2014